NAIL THEORY

Chemistry and the UV-curing process

The structure of acrylates, the UV spectrum that drives curing, the lamp’s measured intensity, and why the process generates heat.

NAIL THEORY

Chemistry and the UV-curing process

Acrylate structure, the UV spectrum that drives curing, the lamp’s measured output

365–405 nm
Curing Wavelength
20–22 mW/cm²
Highest UV intensity
3
Building Blocks of Acrylates
99 seconds
Low heat mode
UV-A
Type of active radiation
01

Chemistry and the UV Curing Process

All UV-activated gel products today are based on acrylates. Acrylates are a broad term for the chemistry behind many of the plastics around us. In the nail industry, what they all have in common is that they are most often found in a liquid, uncured form.

All of our gel products are UV-activated and require UV light at wavelengths between 365nm and 405nm to initiate the curing process. Nailster’s UV lamps emit UV light at these wavelengths to ensure proper curing.

02

Spectrography and Light

When we talk about light and its different wavelengths, we enter the world of spectrography. Spectrography is the technique used to classify light according to its wavelength. The term "nm" stands for nanometer, where 1 meter equals 1 billion nanometers. The light we typically see from a household lamp falls within the visible spectrum, which ranges from 435 to 750 nm. By comparison, X-rays, which are used at the dentist, have a wavelength of around 1 nm. The wavelength defines the distance between two wave crests in the radiation, which means that for red light with a wavelength of 750 nm, there can be up to one and a half million "crests" in one meter.

Radiation is divided into different categories with specific names, such as X-rays, ultraviolet, visible light and infrared (the latter is experienced as heat). The UV light used to cure UV Gel Polish falls within the wavelengths of 365 to 405 nm, placing it in the ultraviolet spectrum, where it is often referred to as UV-A light.

FIG. 1 — RADIATION CATEGORIESArranged from shortest to longest wavelength · not to scale
X-ray
~1 nm
Ultraviolet
UV-C · UV-B
ACTIVE
UV-A · curing
365–405 nm
Visible light
435–750 nm
Infrared
Feels warm
NOTE

It’s worth noting that standard indoor lighting cannot cure our products, so you can safely work under a regular lamp without the risk of accidental curing.

03

UV Lamp Power

UV lamps are often measured in watts, but this does not give an accurate picture of the lamp’s true UV intensity. Watts typically indicate the lamp’s maximum power consumption, which can be compared to judging a car’s performance by its fuel consumption. A more accurate way to measure a UV lamp is to look at its UV intensity. As this can be quite technical, UV intensity is rarely mentioned in the marketing of UV lamps.

The positioning of the LED diodes and the way the UV rays are reflected inside the lamp mean that the intensity varies depending on where in the lamp it is measured. The intensity is highest furthest inside the lamp, at a medium level in the middle, and lowest at the sides.

Position
UV Intensity
Note
Innermost
UV Intensity
20–22 mW/cm²
Note
Maximum strength
Innermost
20–22 mW/cm²
Maximum strength
Center
UV Intensity
12–16 mW/cm²
Note
Medium strength
Center
12–16 mW/cm²
Medium strength
Sides
UV Intensity
10–12 mW/cm²
Note
Lowest strength
Sides
10–12 mW/cm²
Lowest strength
NOTE

The lamp’s “Low heat” function starts at one-third of this intensity and gradually increases over 99 seconds.

04

Sunlight and your nail polish

Sunlight can actually cause your gel products to cure, which is why it’s important to store them in a dark place. You should also avoid doing your nails outdoors, as direct sunlight can affect the curing process and the quality of your result.

STORAGE

Store your products in a dark place.

WORKSPACE

Avoid doing your nails outdoors in direct sunlight.

05

UV-C, UV-B and UV-A

Three types of ultraviolet (UV) radiation — and their role in curing Gel Polish.

UV-C

The germicidal radiation
Not in our lamps

UV-C light is known for its ability to kill bacteria and is often used for disinfection in medical settings. However, this is not a type of light you will be exposed to during your manicure, as our lamps do not emit UV-C rays.

UV-B

The key to sun-kissed skin
Negligible amounts

UV-B is the type of UV radiation that gives your skin its summer glow, but it plays only a minimal role in curing your Gel Polish. Our lamps emit only negligible amounts of UV-B.

UV-A

The Secret Behind Gel Polish
Cures products

UV-A light is what starts the curing process for your gel products. Although UV-A is also associated with an increased risk of skin damage, including cancer, due to its ability to damage DNA, the amount of UV-A you are exposed to during a gel manicure is very small. This exposure can be compared to a few extra hours in the sun, and when UV Gel Polish is used only 1-2 times per month, the risk is considered minimal according to research.

NOTE

For added protection, you can wear UV-protective gloves when applying your gel products. Although this step is not necessary, it can act as an extra safeguard against UV radiation, so you can enjoy your DIY manicure safely and with greater peace of mind.

06

Acrylate Structure

At a chemical level, the acrylates in our products are a blend of three building blocks.

Monomers

Small molecules that can bond together to form longer chains.

Oligomers

Short molecular chains that form the backbone of the polymer structure.

Photoinitiators

Substances that initiate the polymerization process when exposed to UV light.

These are the building blocks of all acrylates and are essential to their function.

07

The Polymerisation Process

From a liquid acrylate blend to a solid, cross-linked polymer on the nail.

STEP A

UV light is applied

365–405 nm reaches the uncured product.

STEP B

Photoinitiators are activated

They act as catalysts in the reaction.

STEP C

The chains link together

Monomers and oligomers bond together.

STEP D

Polymers are formed

Long, cross-linked molecular chains.

STEP E

Firm structure on the nail

The liquid mixture cures into a hard, durable finish.

When UV light is applied, it activates the photoinitiators, which act as catalysts, allowing monomers and oligomers to bond together. This reaction results in the formation of long, cross-linked molecular chains known as polymers. It is this process that transforms the liquid acrylate mixture into a solid, durable form on the nail.

The curing process is therefore essential for achieving the desired result. Complete curing ensures that the polymers have formed a strong matrix, making the UV Gel Polish hard and resistant to wear. Although a product may appear cured on the surface, it is important to ensure that it has fully cured through to the deeper layers to avoid weaknesses in the product’s structure.

08

Heat Build-Up

It is a common misconception that the heat from a UV nail lamp is what “dries” the nails. In fact, it is the UV light itself that cures the nail product. The warmth you feel is simply a natural effect that occurs because UV LEDs also produce heat when they emit light, much like a light bulb that becomes warm.

The curing process for all UV Gel Polish is exothermic, which means it naturally releases a small amount of heat as part of the chemical reaction. Normally, this is not something you will notice. However, in some cases, if a particularly thick layer of product has been applied or if your nails are more sensitive, you may experience a warm sensation.

If you notice a stronger heat sensation, it is important to proceed with care to ensure your comfort. We recommend pausing the curing process briefly and taking a short break. To make the process more pleasant, you can use the lamp’s “Low heat” function. This smart setting starts at a low intensity of around one-third of the full level and gradually increases the power to full capacity over the next 99 seconds. This helps minimize heat build-up, so you can continue creating beautiful nails in a comfortable and safe way.

Phase
Intensity
Purpose
Start
Intensity
⅓ of full strength
Purpose
Where heat generation is typically highest
Start
⅓ of full strength
Where heat generation is typically highest
Gradual Increase
Intensity
Gradual increase
Purpose
Heat is evenly distributed throughout the process
Gradual Increase
Gradual increase
Heat is evenly distributed throughout the process
Conclusion
Intensity
Full capacity
Purpose
Reached in 99 seconds
Conclusion
Full capacity
Reached in 99 seconds
IMPORTANT

If you continue the curing process despite repeated pain caused by the heat, in the most extreme cases you may experience onycholysis, where your nails separate from the nail bed. We therefore recommend using the Low Heat function at the first sign of discomfort, as a precaution.

09

Terminology

A quick glossary of the key terms used on this page.

Acrylates
A broad term for the chemistry behind most of the plastic around us. The foundation of all UV-activated gel products.
Acrylates
A broad term for the chemistry behind most of the plastic around us. The foundation of all UV-activated gel products.
Nanometer (nm)
A unit used to measure wavelength. 1 meter equals 1 billion nanometers.
Nanometer (nm)
A unit used to measure wavelength. 1 meter equals 1 billion nanometers.
Spectrography
The method used to classify light by its wavelength.
Spectrography
The method used to classify light by its wavelength.
Wavelength
The distance between two wave crests of the radiation.
Wavelength
The distance between two wave crests of the radiation.
Monomer
A small molecule that can bond with others to form longer chains.
Monomer
A small molecule that can bond with others to form longer chains.
Oligomer
Short molecular chain — the backbone of the polymer structure.
Oligomer
Short molecular chain — the backbone of the polymer structure.
Photoinitiator
A substance that initiates polymerization when exposed to UV light.
Photoinitiator
A substance that initiates polymerization when exposed to UV light.
Polymer
A long, cross-linked molecular chain. The result of curing.
Polymer
A long, cross-linked molecular chain. The result of curing.
Exothermic
A chemical reaction that releases heat.
Exothermic
A chemical reaction that releases heat.
mW/cm²
Unit of UV intensity — a more accurate measure than watts.
mW/cm²
Unit of UV intensity — a more accurate measure than watts.
Onycholysis
A condition where the nails become loose.
Onycholysis
A condition where the nails become loose.
Nail Theory · Nailster Learning Hub